I want to lookup one array in dataframe using pandas (or anything else) and if the value is found in that column of dataframe then corresponding value in another column of same dataframe is picked up with both recorded into another dataframe. For example, here, lookup column is: arg_array = [111, 222, 333, 444, 777 , 1089 , 3562 ] I know arg_array[1] = lookup_id = 111 exists so that corresponding value (id_number) is recored. But here 1089 and 3562) do not exist so NAN recored. The dataframe array should be: Lookup item Corresponding item 111 OK 222 OK 333 OK 444 OK 777 OK 1089 NAN 3562 NAN It operates using loop - really it's replacing a VLOOKUP so its a vlookup/append but cant get the append to work in a fresh df. I can get the print to work off the loop so left as that but really need help on appending empty dataframe ('new_df'). e.g.: arg_array = arr.array('i', [111, 222, 333, 444, 777 , 1089 , 3562 ]) new_df = [] for item in arg_array: lookup_id = item id_number = get_score_by_id(df_past, lookup_id) if id_number is not None: print(f'{lookup_id}, {id_number}') else: print('NAN') Or should it be something like this where arg_array = arr.array('i', [111, 222, 333, 444, 777 , 1089 , 3562 ]) new_df = [] for item in arg_array: lookup_id = item id_number = get_score_by_id(df_past, lookup_id) if id_number is not None: df_append = (f'{lookup_id}, {id_number}') else: df_append = ('NAN') print(df_append) Where I've added in : df_append Thanks. Continue reading...