First, let's ensure that Windows share is accessible: $ sudo mkdir /mnt/test Let's try mount, but it's fail: $ sudo mount -t cifs //192.168.0.10/work /mnt/test mount: wrong fs type, bad option, bad superblock on //192.168.0.10/work, missing codepage or helper program, or other error (for several filesystems (e.g. nfs, cifs) you might need a /sbin/mount.<type> helper program) In some cases useful info is found in syslog - try dmesg | tail or so. But if provide dummy user/pass (i.e. point exactly 'USERNAME' and 'PASSWD'), mount success: $ sudo mount -t cifs -o username=USERNAME,password=PASSWD //192.168.0.10/work /mnt/test $ ls /mnt/test/*.txt /mnt/test/1.txt $ umount test Now lets try python: $ python -V Python 3.5.2+ $ python >>> import os >>> os.listdir(r'//192.168.0.10/work') Traceback (most recent call last): File "<stdin>", line 1, in <module> FileNotFoundError: [Errno 2] No such file or directory: '//192.168.0.10/work' I'm trying four slashes, backslashes, combine it, with or without r, unicode escaping (bytes(path, "utf-8").decode("unicode_escape")), all this fail with No such file or directory. May be reason of this fail is user/pass, but I have no imagine how add it to UNC. PS. Also I try pysmb library, it's work fine without user/pass. But I don't want using additional lib if it possible. Continue reading...